Deacylative Allylation of Nitroalkanes: Unsymmetric Bisallylation by a Three-Component Coupling
نویسندگان
چکیده
منابع مشابه
Deacylative allylation of nitroalkanes: unsymmetric bisallylation via 3-component coupling
Catalytic Tsuji-Trost allylation has become a ubiquitous method for allylation of active methylene compounds.[1] While monoallylation products are typically formed, bisallylation of malonates and related ketone enolates leads to 1,6-dienes.[2] Given the utility of these 1,6heptadienes in metal-catalyzed cycloisomerization reactions,[3] it would be beneficial if one could perform controlled bisa...
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2010
ISSN: 1433-7851
DOI: 10.1002/anie.201006273